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Scalable quasi-pure MOF membranes for energy-efficient gas separations

  • Sholl, D. S. & Lively, R. P. Seven chemical separations to change the world. Nature 532, 435–437 (2016).

    Article 
    ADS 
    PubMed 

    Google Scholar
     

  • Zhou, S. et al. Asymmetric pore windows in MOF membranes for natural gas valorization. Nature 606, 706–712 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Qian, Q. et al. MOF-based membranes for gas separations. Chem. Rev. 120, 8161–8266 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Jiang, H., Alezi, D. & Eddaoudi, M. A reticular chemistry guide for the design of periodic solids. Nat. Rev. Mater. 6, 466–487 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Lin, R.-B. et al. Molecular sieving of ethylene from ethane using a rigid metal–organic framework. Nat. Mater. 17, 1128–1133 (2018).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Knebel, A. & Caro, J. Metal–organic frameworks and covalent organic frameworks as disruptive membrane materials for energy-efficient gas separation. Nat. Nanotechnol. 17, 911–923 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhou, S. et al. Electrochemical synthesis of continuous metal–organic framework membranes for separation of hydrocarbons. Nat. Energy 6, 882–891 (2021).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Knebel, A. et al. Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids. Nat. Mater. 19, 1346–1353 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Cadiau, A., Adil, K., Bhatt, P. M., Belmabkhout, Y. & Eddaoudi, M. A metal-organic framework–based splitter for separating propylene from propane. Science 353, 137–140 (2016).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Lai, H. W. H. et al. Hydrocarbon ladder polymers with ultrahigh permselectivity for membrane gas separations. Science 375, 1390–1392 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Luo, X. et al. Wrinkled metal-organic framework thin films with tunable Turing patterns for pliable integration. Science 385, 647–651 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Peng, Y. et al. Metal-organic framework nanosheets as building blocks for molecular sieving membranes. Science 346, 1356–1359 (2014).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Xu, L.-H. et al. Highly flexible and superhydrophobic MOF nanosheet membrane for ultrafast alcohol-water separation. Science 378, 308–313 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Ma, X. et al. Zeolitic imidazolate framework membranes made by ligand-induced permselectivation. Science 361, 1008–1011 (2018).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhou, S. et al. Paralyzed membrane: current-driven synthesis of a metal-organic framework with sharpened propene/propane separation. Sci. Adv. 4, eaau1393 (2018).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Hou, Q., Zhou, S., Wei, Y., Caro, J. & Wang, H. Balancing the grain boundary structure and the framework flexibility through bimetallic metal–organic framework (MOF) membranes for gas separation. J. Am. Chem. Soc. 142, 9582–9586 (2020).

    CAS 
    PubMed 

    Google Scholar
     

  • Zhao, Y. et al. Flexible polypropylene-supported ZIF-8 membranes for highly efficient propene/propane separation. J. Am. Chem. Soc. 142, 20915–20919 (2020).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Liang, Y. et al. Large-area ultrathin metal–organic framework membranes fabricated on flexible polymer supports for gas separations. Angew. Chem. Int. Ed. 63, e202404058 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Ma, Q. et al. Ultrafast semi-solid processing of highly durable ZIF-8 membranes for propylene/propane separation. Angew. Chem. Int. Ed. 132, 22093–22098 (2020).

    Article 

    Google Scholar
     

  • Shu, L., Peng, Y., Zhu, C., Li, K. & Yang, W. Metal-organic framework membranes with scale-like structure for efficient propylene/propane separation. Nat. Commun. 15, 10437 (2024).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Dakhchoune, M. et al. Gas-sieving zeolitic membranes fabricated by condensation of precursor nanosheets. Nat. Mater. 20, 362–369 (2021).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Chen, G. et al. Solid-solvent processing of ultrathin, highly loaded mixed-matrix membrane for gas separation. Science 381, 1350–1356 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Datta, S. J. et al. Rational design of mixed-matrix metal-organic framework membranes for molecular separations. Science 376, 1080–1087 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Tan, X. et al. Truly combining the advantages of polymeric and zeolite membranes for gas separations. Science 378, 1189–1194 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Koros, W. J. & Zhang, C. Materials for next-generation molecularly selective synthetic membranes. Nat. Mater. 16, 289–297 (2017).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Napper, D. H. Polymeric Stabilization of Colloidal Dispersions (Academic Press, 1983).

  • de Gennes, P. G. Polymers at an interface; a simplified view. Adv. Colloid Interface Sci. 27, 189–209 (1987).

    Article 

    Google Scholar
     

  • Lin, J.-B. et al. A scalable metal-organic framework as a durable physisorbent for carbon dioxide capture. Science 374, 1464–1469 (2021).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Rodenas, T. et al. Metal–organic framework nanosheets in polymer composite materials for gas separation. Nat. Mater. 14, 48–55 (2015).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Wei, R. et al. Carbon nanotube supported oriented metal organic framework membrane for effective ethylene/ethane separation. Sci. Adv. 8, eabm6741 (2022).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Li, G., Zhang, H. & Han, Y. Applications of transmission electron microscopy in phase engineering of nanomaterials. Chem. Rev. 123, 10728–10749 (2023).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhang, D. et al. Atomic-resolution transmission electron microscopy of electron beam–sensitive crystalline materials. Science 359, 675–679 (2018).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhang, H. et al. Three-dimensional inhomogeneity of zeolite structure and composition revealed by electron ptychography. Science 380, 633–638 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhu, Y. et al. Unravelling surface and interfacial structures of a metal–organic framework by transmission electron microscopy. Nat. Mater. 16, 532–536 (2017).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Ozcan, A. et al. Tuning MOF/polymer interfacial pore geometry in mixed matrix membrane for upgrading CO2 separation performance. Sci. Adv. 10, eadk5846 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Wegst, U. G. K., Bai, H., Saiz, E., Tomsia, A. P. & Ritchie, R. O. Bioinspired structural materials. Nat. Mater. 14, 23–36 (2015).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Batatia, I. et al. A foundation model for atomistic materials chemistry. J. Chem. Phys. 163, 184110 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Hjorth Larsen, A. et al. The atomic simulation environment—a Python library for working with atoms. J. Phys. Condens. Matter 29, 273002 (2017).

    Article 
    PubMed 

    Google Scholar
     

  • Hafner, J. Ab-initio simulations of materials using VASP: density-functional theory and beyond. J. Comput. Chem. 29, 2044–2078 (2008).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Grimme, S. Density functional theory with London dispersion corrections. Wiley Interdiscip. Rev. Comput. Mol. Sci. 1, 211–228 (2011).

    Article 
    CAS 

    Google Scholar
     

  • Dudarev, S. L., Botton, G. A., Savrasov, S. Y., Humphreys, C. J. & Sutton, A. P. Electron-energy-loss spectra and the structural stability of nickel oxide: an LSDA+U study. Phys. Rev. B 57, 1505–1509 (1998).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Limas, N. G. & Manz, T. A. Introducing DDEC6 atomic population analysis: part 2. Computed results for a wide range of periodic and nonperiodic materials. RSC Adv. 6, 45727–45747 (2016).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Rappé, A. K., Casewit, C. J., Colwell, K. S., Goddard, W. A. III & Skiff, W. M. UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations. J. Am. Chem. Soc. 114, 10024–10035 (1992).

    Article 
    ADS 

    Google Scholar
     

  • Boyd, P. G., Moosavi, S. M., Witman, M. & Smit, B. Force-field prediction of materials properties in metal-organic frameworks. J. Phys. Chem. Lett. 8, 357–363 (2017).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Thompson, A. P. et al. LAMMPS – a flexible simulation tool for particle-based materials modeling at the atomic, meso, and continuum scales. Comput. Phys. Commun. 271, 108171 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Abbott, L. J., Hart, K. E. & Colina, C. M. Polymatic: a generalized simulated polymerization algorithm for amorphous polymers. Theor. Chem. Acc. 132, 1334 (2013).

    Article 

    Google Scholar
     

  • Wang, J., Wolf, R. M., Caldwell, J. W., Kollman, P. A. & Case, D. A. Development and testing of a general amber force field. J. Comput. Chem. 25, 1157–1174 (2004).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Semino, R., Ramsahye, N. A., Ghoufi, A. & Maurin, G. Microscopic model of the metal–organic framework/polymer interface: a first step toward understanding the compatibility in mixed matrix membranes. ACS Appl. Mater. Interfaces 8, 809–819 (2016).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Fan, D. et al. Is porosity at the MOF/polymer interface necessarily an obstacle to optimal gas-separation performances in mixed matrix membranes? ACS Mater. Lett. 3, 344–350 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Diaz-Marquez, A., Naskar, S., Fan, D., Eddaoudi, M. & Maurin, G. MOF surface morphology governs interfacial pore architecture and CO2 dynamics in mixed matrix membranes. Chem. Sci. 16, 19519–19531 (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Yang, Q. & Zhong, C. Molecular simulation of carbon dioxide/methane/hydrogen mixture adsorption in metal−organic frameworks. J. Phys. Chem. B. 110, 17776–17783 (2006).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Martin, M. G. & Siepmann, J. I. Transferable potentials for phase equilibria. 1. United-atom description of n-alkanes. J. Phys. Chem. B 102, 2569–2577 (1998).

    Article 
    CAS 

    Google Scholar
     

  • Wells, B. A. & Chaffee, A. L. Ewald summation for molecular simulations. J. Chem. Theory Comput. 11, 3684–3695 (2015).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Peng, D.-Y. & Robinson, D. B. A new two-constant equation of state. Ind. Eng. Chem. Fundam. 15, 59–64 (1976).

    Article 
    CAS 

    Google Scholar
     

  • Nosé, S. A unified formulation of the constant temperature molecular dynamics methods. J. Chem. Phys. 81, 511–519 (1984).

    Article 
    ADS 

    Google Scholar
     

  • Essmann, U. et al. A smooth particle mesh Ewald method. J. Chem. Phys. 103, 8577–8593 (1995).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Song, S. et al. Supplementary data for the paper “Scalable quasi-pure MOF membranes for energy-efficient gas separations”. Zenodo https://doi.org/10.5281/zenodo.20067808 (2026).

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