Li, M. et al. Self-assembled monolayers for interfacial engineering in solution-processed thin-film electronic devices: design, fabrication, and applications. Chem. Rev. 124, 2138–2204 (2024).
Isikgor, F. H. et al. Molecular engineering of contact interfaces for high-performance perovskite solar cells. Nat. Rev. Mater. 8, 89–108 (2023).
Wu, X. et al. Designs from single junctions, heterojunctions to multijunctions for high-performance perovskite solar cells. Chem. Soc. Rev. 50, 13090–13128 (2021).
Jiang, Q. et al. Towards linking lab and field lifetimes of perovskite solar cells. Nature 623, 313–318 (2023).
Jiang, Q. & Zhu, K. Rapid advances enabling high-performance inverted perovskite solar cells. Nat. Rev. Mater. 9, 399–419 (2024).
Best Research-Cell Efficiency Chart (National Renewable Energy Laboratory, 2025); www.nrel.gov/pv/cell-efficiency.html.
Zhang, S. et al. Conjugated self-assembled monolayer as stable hole-selective contact for inverted perovskite solar cells. ACS Mater. Lett. 4, 1976–1983 (2022).
Zhao, K. et al. peri-Fused polyaromatic molecular contacts for perovskite solar cells. Nature 632, 301–306 (2024).
Zhang, X. et al. Advances in inverted perovskite solar cells. Nat. Photon. 18, 1243–1253 (2024).
Chen, H. et al. Improved charge extraction in inverted perovskite solar cells with dual-site-binding ligands. Science 384, 189–193 (2024).
Magomedov, A. et al. Self-assembled hole transporting monolayer for highly efficient perovskite solar cells. Adv. Energy Mater. 8, 1801892 (2018).
Al-Ashouri, A. et al. Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells. Energy Environ. Sci. 12, 3356–3369 (2019).
Al-Ashouri, A. et al. Monolithic perovskite/silicon tandem solar cell with >29% efficiency by enhanced hole extraction. Science 370, 1300–1309 (2020).
Tan, Q. et al. Inverted perovskite solar cells using dimethylacridine-based dopants. Nature 620, 545–551 (2023).
Zhang, S. et al. Minimizing buried interfacial defects for efficient inverted perovskite solar cells. Science 380, 404–409 (2023).
Liu, S. et al. Buried interface molecular hybrid for inverted perovskite solar cells. Nature 632, 536–542 (2024).
Tang, H. et al. Reinforcing self-assembly of hole transport molecules for stable inverted perovskite solar cells. Science 383, 1236–1240 (2024).
Yu, S. et al. Homogenized NiOx nanoparticles for improved hole transport in inverted perovskite solar cells. Science 382, 1399–1404 (2023).
Peng, W. et al. Reducing nonradiative recombination in perovskite solar cells with a porous insulator contact. Science 379, 683–690 (2023).
Liu, M. et al. Compact hole-selective self-assembled monolayers enabled by disassembling micelles in solution for efficient perovskite solar cells. Adv. Mater. 35, 2304415 (2023).
Jiang, W. et al. Spin-coated and vacuum-processed hole-extracting self-assembled multilayers with H-aggregation for high-performance inverted perovskite solar cells. Angew. Chem. Int. Ed. 63, e202411730 (2024).
Jiang, W. et al. π‐Expanded carbazoles as hole‐selective self‐assembled monolayers for high‐performance perovskite solar cells. Angew. Chem. Int. Ed. 61, e202213560 (2022).
Kolb, H. C. et al. Click chemistry: diverse chemical function from a few good reactions. Angew. Chem. Int. Ed. 40, 2004–2021 (2001).
Freudenberg, J. et al. Immobilization strategies for organic semiconducting conjugated polymers. Chem. Rev. 118, 5598–5689 (2018).
Lenz, T. et al. Self-assembled monolayer exchange reactions as a tool for channel interface engineering in low-voltage organic thin-film transistors. Langmuir 28, 13900–13904 (2012).
Gao, C. et al. A dual functional diketopyrrolopyrrole-based conjugated polymer as single component semiconducting photoresist by appending azide groups in the side chains. Adv. Sci. 9, e2106087 (2022).
Jiang, W. et al. Fluoro-substituted DPP-bisthiophene conjugated polymer with azides in the side chains as ambipolar semiconductor and photoresist. Sci. China Chem. 65, 1791–1797 (2022).
Deng, X. et al. Co-assembled monolayers as hole-selective contact for high-performance inverted perovskite solar cells with optimized recombination loss and long-term stability. Angew. Chem. Int. Ed. 61, e202203088 (2022).
Park, S. M. et al. Low-loss contacts on textured substrates for inverted perovskite solar cells. Nature 624, 289–294 (2023).
Zorn, G. et al. X-Ray photoelectron spectroscopy investigation of the nitrogen species in photoactive perfluorophenylazide-modified surfaces. J. Phys. Chem. C 118, 376–383 (2014).
Qu, G. et al. Reformation of thiophene-functionalized phthalocyanine isomers for defect passivation to achieve stable and efficient perovskite solar cells. J. Energy Chem. 67, 263–275 (2022).
Almora, O. et al. On Mott–Schottky analysis interpretation of capacitance measurements in organometal perovskite solar cells. Appl. Phy. Lett. 109, 173903 (2016).
Jang, Y.-W. et al. Intact 2D/3D halide junction perovskite solar cells via solid-phase in-plane growth. Nat. Energy 6, 63–71 (2021).
Li, X. et al. Constructing heterojunctions by surface sulfidation for efficient inverted perovskite solar cells. Science 375, 434–437 (2022).
Rau, U. & Kirchartz, T. Charge carrier collection and contact selectivity in solar cells. Adv. Mater. Interfaces 6, 1900252 (2019).
Wetzelaer, G. J. et al. Trap-assisted non-radiative recombination in organic-inorganic perovskite solar cells. Adv. Mater. 27, 1837–1841 (2015).
Jiang, W. et al. Rational molecular design of multifunctional self-assembled monolayers for efficient hole selection and buried interface passivation in inverted perovskite solar cells. Chem. Sci. 15, 2778–2785 (2024).
Zhan, C. et al. Indium tin oxide induced internal positive feedback and indium ion transport in perovskite solar cells. Angew. Chem. Int. Ed. 63, e202403824 (2024).
Zhou, Y. et al. Advances and challenges in understanding the microscopic structure–property–performance relationship in perovskite solar cells. Nat. Energy 7, 794–807 (2022).
Kerner, R. A. & Rand, B. P. Electrochemical and thermal etching of indium tin oxide by solid-state hybrid organic–inorganic perovskites. ACS Appl. Energy Mater. 2, 6097–6101 (2019).
Roose, B. et al. Critical assessment of the use of excess lead iodide in lead halide perovskite solar cells. J. Phys. Chem. Lett. 11, 6505–6512 (2020).
Shi, L. et al. Gas chromatography-mass spectrometry analyses of encapsulated stable perovskite solar cells. Science 368, eaba2412 (2020).
Penkov, O. V. et al. I. X-Ray Calc 3: improved software for simulation and inverse problem solving for X-ray reflectivity. J. Appl Crystallogr. 57, 555–566 (2024).
