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Dendrite initiation and deflection in biaxially stressed solid electrolytes

  • Janek, J. & Zeier, W. G. A solid future for battery development. Nat. Energy 1, 16141 (2016).

    Article 
    ADS 

    Google Scholar
     

  • Janek, J. & Zeier, W. G. Challenges in speeding up solid-state battery development. Nat. Energy 8, 230–240 (2023).

    Article 
    ADS 

    Google Scholar
     

  • Albertus, P., Babinec, S., Litzelman, S. & Newman, A. Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries. Nat. Energy 3, 16–21 (2018).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Cheng, E. J., Sharafi, A. & Sakamoto, J. Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte. Electrochim. Acta 223, 85–91 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Kazyak, E. et al. Li penetration in ceramic solid electrolytes: operando microscopy analysis of morphology, propagation, and reversibility. Matter 2, 1025–1048 (2020).

    Article 

    Google Scholar
     

  • Han, F. et al. High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes. Nat. Energy 4, 187–196 (2019).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Liu, H. et al. Dendrite formation in solid-state batteries arising from lithium plating and electrolyte reduction. Nat. Mater. 24, 581–588 (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Tian, H.-K., Xu, B. & Qi, Y. Computational study of lithium nucleation tendency in Li7La3Zr2O12 (LLZO) and rational design of interlayer materials to prevent lithium dendrites. J. Power Sources 392, 79–86 (2018).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Tian, H.-K., Liu, Z., Ji, Y., Chen, L.-Q. & Qi, Y. Interfacial electronic properties dictate Li dendrite growth in solid electrolytes. Chem. Mater. 31, 7351–7359 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Porz, L. et al. Mechanism of lithium metal penetration through inorganic solid electrolytes. Adv. Energy Mater. 7, 1701003 (2017).

    Article 

    Google Scholar
     

  • Gao, H. et al. Visualizing the failure of solid electrolyte under GPa-level interface stress induced by lithium eruption. Nat. Commun. 13, 5050 (2022).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Swamy, T. et al. Lithium Metal penetration induced by electrodeposition through solid electrolytes: example in single-crystal Li6La3ZrTaO12 garnet. J. Electrochem. Soc. 165, A3648–A3655 (2018).

    Article 
    CAS 

    Google Scholar
     

  • McConohy, G. et al. Mechanical regulation of lithium intrusion probability in garnet solid electrolytes. Nat. Energy 8, 241–250 (2023).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Zhang, Y. et al. Mechanically driven Li dendrite penetration in garnet solid electrolyte. Nature 652, 912–918 (2026).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Athanasiou, C. E. et al. Operando measurements of dendrite-induced stresses in ceramic electrolytes using photoelasticity. Matter 7, 95–106 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Ning, Z. et al. Dendrite initiation and propagation in lithium metal solid-state batteries. Nature 618, 287–293 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhang, B. et al. Atomic mechanism of lithium dendrite penetration in solid electrolytes. Nat. Commun. 16, 1906 (2025).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Xue, D. et al. Dynamic interplay of dendrite growth and cracking in lithium metal solid-state batteries. J. Mech. Phys. Solids 202, 106197 (2025).

    Article 
    CAS 

    Google Scholar
     

  • Kalnaus, S., Dudney, N. J., Westover, A. S., Herbert, E. & Hackney, S. Solid-state batteries: the critical role of mechanics. Science 381, eabg5998 (2023).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Sandoval, S. E. et al. Electro-chemo-mechanics of anode-free solid-state batteries. Nat. Mater. 24, 673–681 (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Flatscher, F. et al. Deflecting dendrites by introducing compressive stress in Li7La3Zr2O12 using ion implantation. Small 20, 2307515 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Thomas, C. et al. Stress engineering for crack and dendrite prevention in solid electrolytes via ion implantation. Cell Rep. Phys. Sci. 6, 102544 (2025).

  • Xu, X. et al. Heterogeneous doping via nanoscale coating impacts the mechanics of Li intrusion in brittle solid electrolytes. Nat. Mater. 25, 627–634 (2026).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Yu, Z. et al. Dendrite suppression in garnet electrolytes via thermally induced compressive stress. Joule 10, 102232 (2026).

    Article 
    CAS 

    Google Scholar
     

  • Liu, X. et al. Local electronic structure variation resulting in Li ‘filament’ formation within solid electrolytes. Nat. Mater. 20, 1485–1490 (2021).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhu, C. et al. Understanding the evolution of lithium dendrites at Li6.25Al0.25La3Zr2O12 grain boundaries via operando microscopy techniques. Nat. Commun. 14, 1300 (2023).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Fincher, C. D. et al. Controlling dendrite propagation in solid-state batteries with engineered stress. Joule 6, 2794–2809 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Anderson, T. L. Fracture Mechanics—Fundamentals and Applications (Taylor & Francis, 2017).

  • Cook, R. F. & DelRio, F. W. Determination of ceramic flaw populations from component strengths. J. Am. Ceram. Soc. 102, 4794–4808 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Yang, L., Gao, Y., Chen, Y. & Ding, B. Mechanisms of transverse bowl-shaped crack in all solid-state batteries. Eng. Fract. Mech. 321, 111117 (2025).

    Article 

    Google Scholar
     

  • Siniscalchi, M. et al. Initiation of dendritic failure of LLZTO via sub-surface lithium deposition. Energy Environ. Sci. 17, 2431–2440 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Fuchs, T., Haslam, C. G., Richter, F. H., Sakamoto, J. & Janek, J. Evaluating the use of critical current density tests of symmetric lithium transference cells with solid electrolytes. Adv. Energy Mater. 13, 2302383 (2023).

    Article 
    CAS 

    Google Scholar
     

  • Klimpel, M., Zhang, H., Kovalenko, M. V. & Kravchyk, K. V. Standardizing critical current density measurements in lithium garnets. Commun. Chem. 6, 192 (2023).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Famprikis, T., Canepa, P., Dawson, J. A., Islam, M. S. & Masquelier, C. Fundamentals of inorganic solid-state electrolytes for batteries. Nat. Mater. 18, 1278–1291 (2019).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Bardeen, J. Electrical conductivity of metals. J. Appl. Phys. 11, 88–111 (1940).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Counihan, M. J. et al. The phantom menace of dynamic soft-shorts in solid-state battery research. Joule 8, 64–90 (2023).

    Article 

    Google Scholar
     

  • Wang, C. et al. Identifying soft breakdown in all-solid-state lithium battery. Joule 6, 1770–1781 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Guo, W. et al. In-situ optical observation of Li growth in garnet-type solid state electrolyte. Energy Storage Mater. 41, 791–797 (2021).

    Article 
    ADS 

    Google Scholar
     

  • Yu, S. & Siegel, D. J. Grain boundary contributions to Li-ion transport in the solid electrolyte Li7La3Zr2O12 (LLZO). Chem. Mater. 29, 9639–9647 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Yu, S. & Siegel, D. J. Grain boundary softening: a potential mechanism for lithium metal penetration through stiff solid electrolytes. ACS Appl. Mater. Interfaces 10, 38151–38158 (2018).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Yildirim, C. et al. Understanding the origin of lithium dendrite branching in Li6.5La3Zr1.5Ta0.5O12 solid-state electrolyte via microscopy measurements. Nat. Commun. 15, 8207 (2024).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Xie, X. et al. Lithium expulsion from the solid-state electrolyte Li6.4La3Zr1.4Ta0.6O12 by controlled electron injection in a SEM. ACS Appl. Mater. Interfaces 10, 5978–5983 (2018).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Krauskopf, T. et al. Lithium-metal growth kinetics on LLZO garnet-type solid electrolytes. Joule 3, 2030–2049 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Wang, S. et al. Effect of H+ exchange and surface impurities on bulk and interfacial electrochemistry of garnet solid electrolytes. Chem. Mater. 36, 6849–6864 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Krauskopf, T., Richter, F. H., Zeier, W. G. & Janek, J. Physicochemical concepts of the lithium metal anode in solid-state batteries. Chem. Rev. 120, 7745–7794 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Wang, T. et al. Fatigue of Li metal anode in solid-state batteries. Science 388, 311–316 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Dixit, M. B. et al. Polymorphism of garnet solid electrolytes and its implications for grain-level chemo-mechanics. Nat. Mater. 21, 1298–1305 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Luo, Q. & Jones, A. H. High-precision determination of residual stress of polycrystalline coatings using optimised XRD-sin2ψ technique. Surf. Coat. Technol. 205, 1403–1408 (2010).

    Article 
    CAS 

    Google Scholar
     

  • Yu, S. et al. Elastic properties of the solid electrolyte Li7La3Zr2O12 (LLZO). Chem. Mater. 28, 197–206 (2016).

    Article 
    CAS 

    Google Scholar
     

  • Newville, M. et al. LMFIT: non-linear least-squares minimization and curve-fitting for Python. Zenodo https://doi.org/10.5281/zenodo.15014437 (2025).

  • Santhosha, A. L., Medenbach, L., Buchheim, J. R. & Adelhelm, P. The indium−lithium electrode in solid-state lithium-ion batteries: phase formation, redox potentials, and interface stability. Batter. Supercaps 2, 524–529 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Coelho, A. A. TOPAS and TOPAS-Academic: an optimization program integrating computer algebra and crystallographic objects written in C++. J. Appl. Crystallogr. 51, 210–218 (2018).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Kataoka, K. & Akimoto, J. Lithium-ion conductivity and crystal structure of garnet-type solid electrolyte Li7xLa3Zr2−xTaxO12 using single-crystal. J. Ceram. Soc. Jpn 127, 521–526 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Fairley, N. et al. Systematic and collaborative approach to problem solving using X-ray photoelectron spectroscopy. Appl. Surf. Sci. Adv. 5, 100112 (2021).

    Article 

    Google Scholar
     

  • Bunger, A. P. & Detournay, E. Asymptotic solution for a penny-shaped near-surface hydraulic fracture. Eng. Fract. Mech. 72, 2468–2486 (2005).

    Article 
    ADS 

    Google Scholar
     

  • Zhang, X., Detournay, E. & Jeffrey, R. Propagation of a penny-shaped hydraulic fracture parallel to the free-surface of an elastic half-space. Int. J. Fract. 115, 125–158 (2002).

    Article 
    ADS 

    Google Scholar
     

  • Cui, T., Lee, S. & Wang, S. Dendrite initiation and deflection in biaxially stressed solid electrolytes. Zenodo https://doi.org/10.5281/zenodo.20373114 (2026).

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